Zinedine Zidane's side host Javier Calleja's side on Saturday afternoon, looking to close the gap on league leaders Barcelona. Madrid are fourth, currently 16 points behind their rivals in La Liga.
The 32-year-old American, who last fought in November when he beat Bermane Stiverne with a first-round knockout to retain his WBC title, was arrested in Alabama last June.
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The former heavyweight champion, who has not fought since dethroning Wladimir Klitschko back in November 2015, announced on Twitter on Wednesday that he would seek to regain his licence.